[Fe2(μ-O)(3,5-dimethylpyrazole)6Cl4] | 1242187-06-9

• 英文名称: [Fe2(μ-O)(3,5-dimethylpyrazole)6Cl4]
• CAS: 1242187-06-9
• 化学式: C₃₀H₄₈Cl₄Fe₂N₁₂O
• 分子量: 846.297
• InChiKey: TXUJOLFMWDEWPI-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Fe(3,5-dimethylpyrazole)3Cl]Cl 在 air 作用下， 以 乙腈 为溶剂， 以75%的产率得到[Fe2(μ-O)(3,5-dimethylpyrazole)6Cl4]
  参考文献：
  名称：

  Oxidation of the iron(II) complex with 3,5-dimethylpyrazole by air in acetonitrile and dibenzyl ether

  摘要：

  The reaction of the polymeric complex FeCl2(NCMe)(2) (1) with 3,5-dimethylpyrazole (Hdmpz) yields the tetrahedral complex [Fe(Hdmpz)(3)Cl]Cl (2), which is oxidized by air in acetonitrile to give [Fe(Hdmpz)(3)Cl-2](2)(mu-O) (3). The reaction of FeCl3 center dot 6H(2)O with Hdmpz also leads to complex 3. The oxidation of complex 2 in a dichloromethane solution of dibenzyl ether gives the complex (Hdmpz)FeCl2[eta(2)-N,O-(dmpz)C(O)H(Ph)] (4), which contains a coordinated tetrahedral intermediate product of condensation of Hdmpz and benzaldehyde. The structures of complexes 1-4 are discussed on the basis of X-ray crystallographic data.

  DOI：

  10.1134/s003602360912016x