| 1065641-39-5

• CAS: 1065641-39-5
• 化学式: C₂₄H₁₇Fe₄NO₉Te₂
• 分子量: 941.988
• InChiKey: KYBJLDONHITPJL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二茂铁乙炔 、 Fe3(μ3-Te)2(CO)9 、 trimethylamine-N-oxide dihydrate 以 二氯甲烷 为溶剂， 以0%的产率得到
  参考文献：
  名称：

  Formation of N-Methylated Cyclic Ligand Systems from Unusual Reactions between Trimethylamine N-Oxide and Acetylenes on Fe₃Te₂(CO)₉ and Contrast with Reactions on Fe₃E₂(CO)₉(E = S, Se)

  摘要：

  Activation of C-H bonds of N-methyl groups has been achieved on cluster support. Use of a noncoordinating solvent in the reaction of Me3NO center dot 2H2O, acetylenes, and Fe3Te2(CO)(9) leads to activation of N-methyl groups of Me3NO and formation of N,N-dimethyldihydropyrrole (1) and N,M-dimethyl-hexahydropyrimidine (2) ring systems. The NMe3 ligand, resulting from TMNO, is retained on the metal cluster due to the absence of a coordinating solvent and reacts with incoming acetylenes. In contrast, activation of the N-methyl groups Of Me3NO is not observed in the reaction using Fe3S2(CO)(9), which yields complexes with vinylferrocene (3) and 1,4-diferrocenylbuta-1,3-diene-2,3-dithio (4) units attached to Fe2S2(CO)(6). All new compounds have been structurally characterized by single-crystal X-ray diffraction studies.

  DOI：

  10.1021/om701290c