[bis(triphenylphosphoranylidene)ammonium][(catBOBcat)*(OAc)] | 858865-56-2

• 英文名称: [bis(triphenylphosphoranylidene)ammonium][(catBOBcat)*(OAc)]
• 英文别名: [PPN][(catBOBcat)*(OAc)]
• CAS: 858865-56-2
• 化学式: C₁₄H₁₁B₂O₇*C₃₆H₃₀NP₂
• 分子量: 851.448
• InChiKey: NZMIFUXGORJSCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  双联邻苯二酚硼酸酯 、 二(三苯基膦)铵乙酸盐 以 二氯甲烷 为溶剂， 生成 [bis(triphenylphosphoranylidene)ammonium][(catBOBcat)*(OAc)]
  参考文献：
  名称：

  Complementary anion binding by bidentate boron-containing Lewis acids

  摘要：

  Anion binding by the pyroborates (catB)(2)O (1, cat = O2C6H4-1,2) and (S,S-Ph2C2H2O2B)(2)O (2) has been investigated by spectroscopic, structural and titration methods. 1 has been shown to act as a bifunctional Lewis acid, exemplified by the complementary (1:1) binding of bidentate bases such as acetate and dihydrogen phosphate. The former complex has been characterized in the solid state by X-ray diffraction and a binding constant of 1500 +/- 550 M-1 determined in chloroform solution. The reaction of 2 with acetate, by contrast, leads to breakdown of the Lewis acid chelate and to the formation of the homochiral borate anion [(S,S-Ph2C2H2O2)(2)B](-) in good yield (84% based on the chiral component). (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.01.015