| 99449-53-3

• CAS: 99449-53-3
• 化学式: C₂₉H₂₅Cl₂N₂OPRu
• 分子量: 620.48
• InChiKey: OYXWDSSTAHYZLN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  carbon monoxide;dichlororuthenium;triphenylphosphane 在 吡啶 作用下， 以 吡啶 为溶剂， 生成
  参考文献：
  名称：

  钌（II）与三苯基膦或三苯基ar和其他单齿配体的配合物

  摘要：

  摘要一些五配位钌（II）配合物的合成与研究。已经描述了[Ru（MPh 3）（C 6 H 5 CHO）2 Cl 2]和[Ru（MPh 3）2（CO）Cl 2]（其中M ＝ P或As）。描述了[Ru（MPh3）（C6H5CHO）2Cl2]与N，N-二甲基甲酰胺，二甲基亚砜和吡啶的反应以及[Ru（MPh3）2（CO）Cl2]与吡啶的反应。

  DOI：

  10.1016/s0277-5387(00)86973-9

文献信息

• Aryldiazenido ruthenium(II) complexes. Structure and characterization of p-tolyldiazenido carbonyl-ruthenium(II) coordination compound and its reaction with pyrazole and pyridine
  作者：Jan G. Małecki、Anna Maroń、Tadeusz Groń、Monika Oboz

  DOI：10.1016/j.poly.2014.06.014

  日期：2014.10

  The p-tolyldiazenido ruthenium [RuCl2(CO)(PPh3)(2)(N2PhCH3)] (1) and [RuCl2(CO)(PPh3)(2)(HPz)(2)] (2) and [RuCl2(CO)(PPh3)(py)] (3) coordination compounds were synthesized and characterized by IR, H-1, C-13, P-31 NMR, electronic absorption and X-ray crystallography. The structural parameters showed the bent coordination mode of N2PhCH3 ligand in complex (1) but the measured magnetic susceptibility showed a week response to the ac applied magnetic field and a lack of a Curie-Weiss region means diamagnetism. The most spectacular observation concerns the ZFC-FC splitting, however, the product chi center dot T versus temperature T is revealing none to the anomaly. The reactions of (1) with pyrazole and pyridine lead to monophosphine complexes so it may be used as a precursor for the synthesis of the new monophosphine carbonyl ruthenium coordination compounds(II). (C) 2014 Elsevier Ltd. All rights reserved.