[(p-t-butylcalix[4]arene(OMe)2(O)2)Fe(CN(t)Bu)] | 199684-35-0

• 英文名称: [(p-t-butylcalix[4]arene(OMe)2(O)2)Fe(CN(t)Bu)]
• CAS: 199684-35-0
• 化学式: C₅₁H₆₇FeNO₄
• 分子量: 813.944
• InChiKey: IVSXHCLWZLOWMZ-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  [(p-t-butylcalix[4]arene(OMe)2(O)2)Fe] 、 异氰酸叔丁酯 以 乙醚 为溶剂， 以84.9%的产率得到[(p-t-butylcalix[4]arene(OMe)2(O)2)Fe(CN(t)Bu)]
  参考文献：
  名称：

  Iron−Carbene Bonded to a Planar Tetraoxo Surface Defined by Dimethoxy-p-tert-butylcalix[4]arene Dianion

  摘要：

  A reactive coordinatively unsaturated iron(II) bonded to a quasi-planar O-4 environment in [calix[4](OMe)(2)(O)(2)Fe] (2) has been obtained from the reaction of the free ligand 1 with Fe(2)Mes(4) (Mes = 1,3,5-Me3C6H2). The reaction of 2, which adds a variety of monodentate ligands, [calix[4](OMe)(2)(O)(2)FeL] (L = thf, 3; (BuNC)-N-t, 4), with Ph2CN2 led to the first high-spin iron(II) carbene bonded to an oxo matrix, [calix[4](OMe)(2)(O)(2)Fe=CPh2] (5).

  DOI：

  10.1021/om970751i