2-benzyl-η,η(5)-fulvalenedimanganesehexacarbonyl | 175405-46-6

• 英文名称: 2-benzyl-η,η(5)-fulvalenedimanganesehexacarbonyl
• CAS: 175405-46-6
• 化学式: C₂₃H₁₄Mn₂O₆
• 分子量: 496.237
• InChiKey: SITJKEQZTKZQPF-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  2-benzoyl-η,η(5)-fulvalenedimanganesehexacarbonyl 在 盐酸 、 lithium aluminium tetrahydride 、 三氯化铝 作用下， 以 乙醚 为溶剂， 以55%的产率得到2-benzyl-η,η(5)-fulvalenedimanganesehexacarbonyl
  参考文献：
  名称：

  Acetylation and benzoylation of ?5,?5-fulvalenedimanganesehexacarbonyl

  摘要：

  eta(5) eta(5)-Fulvalenedimanganesehexacarbonyl (dicymantrenyl) was acetylated and benzoylated by RC(O)Cl+AlCl3 in CH2Cl2, under conditions of the Friedel-Crafts reaction. The reaction involves both nonequivalent positions of the cyclopentadienyl rings to give mixtures of two isomeric ketones. When using an excess of the acetylating mixture, diacetyl derivatives of dicymantrenyl were obtained.

  DOI：

  10.1007/bf00707231