[bis(2-(2-oxy-5-nitrophenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl)bis(hexafluoroacetylacetonate)dicopper(II)] | 626206-59-5

• 英文名称: [bis(2-(2-oxy-5-nitrophenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl)bis(hexafluoroacetylacetonate)dicopper(II)]
• CAS: 626206-59-5
• 化学式: CH₂Cl₂*C₃₆H₃₂Cu₂F₁₂N₆O₁₂
• 分子量: 1180.69
• InChiKey: UIHISSGBBXQFEF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-(5-bromo-2-hydroxy-3-nitro-phenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl 、 二氯甲烷 、 copper(II) hexafluoroacetylacetonate 以 二氯甲烷 为溶剂， 以65%的产率得到[bis(2-(2-oxy-5-nitrophenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl)bis(hexafluoroacetylacetonate)dicopper(II)]
  参考文献：
  名称：

  Synthesis of 2-iminonitroxide-substituted phenols and pyridine-3-oles.

  摘要：

  Methods for the synthesis of a new family of nitronylnitroxides, iminonitroxides, and their precursors with 2-hydroxyphenyl or 3-hydroxypyridin-2-yl substituents in the side chain have been developed. Five heterospin chelates of Cu(II) with deprotonated iminonitroxides have been isolated. Their structure and magnetic properties have been studied. In all complexes, ferromagnetic intramolecular exchange interactions take place (J similar to 40-350 cm(-1)) (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00228-6