5-tert-butyl-5-ferrocenyl-1,2-diphenylcyclopenta-1,3-diene | 204327-41-3

• 英文名称: 5-tert-butyl-5-ferrocenyl-1,2-diphenylcyclopenta-1,3-diene
• 英文别名: 1,2-diphenyl-5-ferrocenyl-5-tert-butylcyclopentadiene
• CAS: 204327-41-3
• 化学式: C₃₁H₃₀Fe
• 分子量: 458.426
• InChiKey: BZUPAROIIUVDMQ-FBHGDYMESA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 拓扑面积：
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反应信息

• 作为产物：
  描述：

  3-tert-butyl-3-ferrocenylcyclopropene 、 二苯基乙炔 以 甲苯 为溶剂， 以31%的产率得到5-tert-butyl-5-ferrocenyl-1,2-diphenylcyclopenta-1,3-diene
  参考文献：
  名称：

  Klimova; Alvarez; Klimova, Russian Journal of General Chemistry, 1998, vol. 68, # 6, p. 949 - 957

  摘要：

  DOI：

文献信息

• Formation of acetylenic compounds and ring transformations of 3-alkyl-3-ferrocenylcyclopropenes in the reaction with 1,3-diphenylisobenzofuran
  作者：Elena I Klimova、Lena Ruı́z Ramı́rez、Rafael Moreno Esparza、Tatiana Klimova Berestneva、Marcos Martinez Garcı́a、Natalya N Meleshonkova、Andrei V Churakov

  DOI：10.1016/s0022-328x(97)00670-0

  日期：1998.5

  The reaction of 3-ferrocenyl-3-methylcyclopropene with 1,3-diphenylisobenzofuran leads to the formation of exo- and endo -1,4-epoxy-2-ethynyl-2-ferrocenyl-1,4-diphenyltetralines as the main products in addition to the isomeric Diels - Alder exo-adducts. At the same time, 3-tert-butyl- and 3-(1-adamantyl)-3-ferrocenylcyclopropenes form the endo- and exo-adducts of 3-alkyl-1,2-(1-propene-1,3-diyl)ferrocene. The structures of the acetylenic compounds and of the adduct containing a Bu-t-substituent are established by X-ray structural analysis. A possible reaction pathway via intermediate zwitter-ion is discussed. (C) 1998 Elsevier Science S.A. All rights reserved.