dibromo(1H-indole-2,3-dione 3-thiosemicarbazone)(4-aminobenzenesulfamide)copper(II) | 945948-04-9

• 英文名称: dibromo(1H-indole-2,3-dione 3-thiosemicarbazone)(4-aminobenzenesulfamide)copper(II)
• 英文别名: dibromo(isatin β-thiosemicarbazone)(streptocid)copper(II)
• CAS: 945948-04-9
• 化学式: C₁₅H₁₆Br₂CuN₆O₃S₂
• 分子量: 615.816
• InChiKey: DKJXUQNYENTFJP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dibromo(1H-indole-2,3-dione 3-thiosemicarbazone)(4-aminobenzenesulfamide)copper(II) pentahydrate 以 neat (no solvent) 为溶剂， 生成 dibromo(1H-indole-2,3-dione 3-thiosemicarbazone)(4-aminobenzenesulfamide)copper(II) 、 水
  参考文献：
  名称：

  Sulfanilamide-containing coordination compounds of Cu(II) with isatin and N-methylisatin thiosemicarbazones

  摘要：

  Isatin (L-1) and N-methylisatin (L-2) beta-thiosemicarbazones react in ethanol with Cu(II) chloride and bromide in the presence of sulfanilamide (Streptocid, St(1)), N-acetylsulfanilamide (Sulfacyl, Sf(2)), Norsulfazole (Sf(3)), Aethazolum (Sf(4)), and Sulfadimesine (Sf(5)) to form coordination compounds Cu(Sf(1-5))L(1-2)x,. nH(2)O (X = Cl, Br; n = 2-5). All the complexes have a monomeric structure. Thiosemicarbazones L-1 and L-2 in these complexes are tridentate O,N,S ligands, and sulfanilamides Sf(1-5) are monodentate ligands. Thermolysis of the substances involves the steps of dehydration (70-95 degrees C) and complete decomposition (410-530 degrees C).

  DOI：

  10.1134/s1070363206090179