(4-benzylpiperidineglyoximate)chloroaquacadmium(II) | 1122592-33-9

• 英文名称: (4-benzylpiperidineglyoximate)chloroaquacadmium(II)
• CAS: 1122592-33-9
• 化学式: C₁₄H₂₀CdClN₃O₃
• 分子量: 426.194
• InChiKey: OXCWDFZUTGKKGM-SHOSYNEKSA-L

物化性质

• 熔点：
  161 °C (decomp)

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  水 、 aqueous cadmium chloride 、 4-benzylpiperidineglyoxime 在 NaOH 作用下， 以 乙醇 、 水 为溶剂， 以58%的产率得到(4-benzylpiperidineglyoximate)chloroaquacadmium(II)
  参考文献：
  名称：

  Synthesis and characterization of new (E,E)-dioximes and their divalent metal complexes

  摘要：

  Two new soluble vic-dioxime ligands, 4-isopropylanilineglyoxime ((LH2)-H-1) and 4-benzylpiperidineglyoxime ((LH2)-H-2) were prepared by reacting 4-isopropylaniline and 4-benzylpiperidine with anti-chloroolyoxime. Ten metal complexes were obtanied by reacting both ligands with Cu(II), Ni(II), Co(II), Zn(II), and Cd(II) cations. The ligands and their metal complexes were elucidated by elemental analysis, IR, UV-vis, H-1 NMR, and C-13 NMR and also magnetic moments of the complexes were determined.

  DOI：

  10.1134/s1070328407120093