| 233767-61-8

• CAS: 233767-61-8
• 化学式: C₁₄H₁₈Cl₂CuN₁₀O₈
• 分子量: 588.811
• InChiKey: HBTWTQRISGUXPR-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  copper dichloride 、 N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidine-2-yl)-glycinatopotassium 以 水 为溶剂， 生成
  参考文献：
  名称：

  Solution–solid-state study of the system Cu(II)/N-2-(4-amino-1,6-dihydro-1-methyl-5-nitroso-6-oxopyrimidinyl)glycine.

  摘要：

  An aqueous solution-solid-state study of the Cu(II)/HL system (HL=N-2-(4-amino-1,6-dihydro-1-methyl-5-nitroso-6-oxopyrimidinyl)glycine) is reported. The solution studies have been carried out on the protonation equilibria of HL and the Cu(II)/HL system, at molar ratios of 1:1 and 1:5. Two complexes were obtained in the solid state, Cu(II)/HL molar ratio=1:1, and were characterized by spectroscopic and X-ray single-crystal diffraction techniques. Mononuclear complex 1 [(CuCl2(HL)(2)](n) crystallizes with a hexacoordinated coordination mode around the Cu(II) ion, while complex 2 [CuCl(L)(H2O)(2)] is an infinite polynuclear ladder-like chain, with a distorted asymmetric square-based bipyramid. None of those crystalline complexes were detected in the solution study. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00034-0