[(η5-1,2,3,4,7-pentamethylindenyl)RhI2]2 | 1002356-67-3

• 英文名称: [(η5-1,2,3,4,7-pentamethylindenyl)RhI2]2
• 英文别名: [(η5-C9H2Me5)RhI2]2
• CAS: 1002356-67-3
• 化学式: C₂₈H₃₄I₄Rh₂
• 分子量: 1084.01
• InChiKey: QURGDAUSILOTNS-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  thallium ortho-dicarbollide 、 二氯甲烷 、 [(η5-1,2,3,4,7-pentamethylindenyl)RhI2]2 以 乙腈 为溶剂， 以58%的产率得到(η-7,8-dicarbollyl)(η-1,2,3,4,7-pentamethylindenyl)rhodium*0.5CH2Cl2
  参考文献：
  名称：

  1,2,3,4,7-Pentamethylindenyl complex [(η5-C9H2Me5)RhI2]2 as a synthon for the [(η5-C9H2Me5)Rh]2+ fragment

  摘要：

  碘化物络合物[(η5-C9H2Me5)RhI2]2 (1) 或乙腈络合物[(η5-C9H2Me5)Rh(MeCN)3]2+ 与 Tl[Tl(η-7,8-C2B9H11)] 反应生成了罗达硼烷 (η5-C9H2Me5)Rh(7,8-C2B9H11)(2)。通过硝基甲烷溶胶 [(η5-C9H2Me5)Rh(MeNO2)3]2+与夹心化合物 Cp*Fe(η-C5H3Me2BMe) 的反应，合成了具有桥接硼苯配体的阳离子三迭代配合物 [Cp*Fe(μ-η:η-C5H3Me2BMe)Rh(η5-C9H2Me5)]2+（3）。通过 X 射线衍射确定了 2 的结构。

  DOI：

  10.1007/s11172-008-0215-4
• 作为产物：
  描述：

  [(η5-1,2,3,4,7-pentamethylindenyl)Rh(1,5-cyclooctadiene)] 、 碘 以 乙醚 为溶剂， 以98%的产率得到[(η5-1,2,3,4,7-pentamethylindenyl)RhI2]2
  参考文献：
  名称：

  (1,2,3,4,7-Pentamethylindenyl)rhodium complexes with arene ligands

  摘要：

  The reaction of (eta(5)-C9H2Me5)Rh(1,5-C8H12) (1) with I-2 gives the iodide complex [(eta(5)-C9H2Me5)RhI2](2) (2). The solvate complex [(eta 5-C9H2Me5)Rh(MeNO2)(3)](2+) (generated in situ by treatment of 2 with Ag+ in nitromethane) reacts with benzene and its derivatives giving the dicationic arene complexes [(eta(5)-C9H2Me5)Rh(arene)](2+) [arene = C6H6 (3a), C6Me6 (3b), C6H5OMe (3c)]. Similar reaction with the borole sandwich compound CpRh(eta(5)-C4H4BPh) results in the arene-type complex [CpRh(mu-eta(5):eta(6)-C4H4BPh)Rh(eta(5)-C9H2Me5)](2+) (4). Treatment of 2 with CpT1 in acetonitrile affords cation [(eta(5)-C9H2Me5)RhCp](broken vertical bar) (5). The structure of [3c](BF4)(2) was determined by X-ray diffraction. The electrochemical behaviour of complexes prepared was studied. The rhodium-benzene bonding in series of the related complexes [(ring)Rh(C6H6)](2+) (ring = Cp, Cp*, C9H7, C9H2Me5) was analyzed using energy and charge decomposition schemes. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.10.006