(μ-Cl)Ru3(CO)9[μ3-η4-H2CCC(H)CH2] | 669048-78-6

• 英文名称: (μ-Cl)Ru3(CO)9[μ3-η4-H2CCC(H)CH2]
• CAS: 669048-78-6
• 化学式: C₁₃H₅ClO₉Ru₃
• 分子量: 643.84
• InChiKey: YZPVESRTNVNZDP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  丁炔二醇 、 盐酸 、 十二羰基三钌 在 KOH 作用下， 以 甲醇 、 水 为溶剂， 以10%的产率得到(μ-Cl)Ru3(CO)9[μ3-η4-H2CCC(H)CH2]
  参考文献：
  名称：

  Reaction of Ru3(CO)12 with but-2-yn-1,4-diol in CH3OH/KOH solution. Crystal structure of (μ-Cl)Ru3(CO)9[μ3-η4-H2CCC(H)CH2]

  摘要：

  The reaction of Ru-3(CO)(12) with but-2-yn-1,4-diol (HOCH(2)Cequivalent toCCH(2)OH, BUD) in CH3OH/KOH followed by acidification with HCl leads to four products, one of which has been identified as the title complex (mu-Cl)Ru-3(CO)(9)[mu(3)-eta(4)-H2CCC(H)CH2]. This is an open cluster containing a bridging Cl atom on the open side and a C4H5 moiety bound to all the metals. The structure of the complex has been determined by X-ray analysis.The thermal reaction of Ru-3(CO)(12) with BUD has been revisited for a comparison with the results in alkaline solution. The main product is the allylic derivative HRu3(CO)(9)[HCCHCCHO]. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.09.023