CuCl(N-isopropylimidazolidine-2-thione) | 105322-85-8

• 英文名称: CuCl(N-isopropylimidazolidine-2-thione)
• CAS: 105322-85-8
• 化学式: C₁₂H₂₄ClCuN₄S₂
• 分子量: 387.48
• InChiKey: JUYQQEGWWHXIKL-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  CuCl(N-isopropylimidazolidine-2-thione) 以 neat (no solvent, solid phase) 为溶剂， 生成 dichlorobis(1-isopropylimidazolidine-2-thione)copper(II) 、 chlorobis(1-isopropylimidazolidine-2-thione)copper(II) cation 、 bis(1-isopropylimidazolidine-2-thione)copper(I) cation
  参考文献：
  名称：

  Four-co-ordinated copper(II) species obtained by X-ray irradiation of a three-co-ordinated copper(I) complex: a single crystal EPR study

  摘要：

  X-Ray irradiation of a single crystal of chlorobis(1-isopropylimidazolidine-2-thione)copper(I) led to the formation of two copper(II) species whose structures were studied by EPR spectroscopy. The EPR parameters provide information on the structural changes which characterize the formation of the four-co-ordinated copper(II) species when the three-co-ordinated copper(I) precursor reacts with radiogenic radicals formed during the irradiation and provide insight into the reaction mechanism.

  DOI：

  10.1039/b004294n