[(η(5)-C5H5)Fe(η(5)-C5H4CH2PPh2Et)](+)I(-) | 254730-02-4

• 英文名称: [(η(5)-C5H5)Fe(η(5)-C5H4CH2PPh2Et)](+)I(-)
• CAS: 254730-02-4
• 化学式: C₂₅H₂₆FeP*I
• 分子量: 540.207
• InChiKey: UYMDOHXLGLEWSO-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  ((diphenylphosphino)methyl)ferrocene 、 碘乙烷 以 二氯甲烷 为溶剂， 生成 [(η(5)-C5H5)Fe(η(5)-C5H4CH2PPh2Et)](+)I(-)
  参考文献：
  名称：

  Coordination chemistry and X-ray crystal structure of (ferrocenylmethyl)diphenylphosphine, FcCH2PPh2 [Fc=(η5-C5H5)Fe(η5-C5H4)]

  摘要：

  The known ferrocenyl-phosphine FcCH(2)PPh(2) has been synthesised by a new route, involving reaction of the hydroxymethylphosphine Ph2PCH2OH (generated in situ by reaction of air-stable [Ph2P(CH2OH)(2)]Cl and KOH) with [FcCH(2)NMe(3)]I. An X-ray crystal structure determination has been carried out on the product. Reaction of FcCH(2)PPh(2) with 0.5 molar equivalent of [RuCl2(eta(6)-p-cymene)](2) gave the ruthenium-phosphine complex [RuCl2(eta(6)-p-cymene)(FcCH(2)PPh(2))] by a chloride bridge-splitting reaction. The product was also fully characterised, including an X-ray crystal structure. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00284-4