(1-(ferrocenylethynyl)-4-ethynylbenzenyl)-acridine | 1228183-48-9

• 英文名称: (1-(ferrocenylethynyl)-4-ethynylbenzenyl)-acridine
• CAS: 1228183-48-9
• 化学式: C₃₃H₂₁FeN
• 分子量: 487.383
• InChiKey: ADDVBJWEEMENKN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  9-氯吖啶 、 (4-ethynylphenyl)ethynylferrocene 在 PdCl₂(PPh₃)2 、 CuI 作用下， 以 tetrahydrofuran 、 triethylamine 为溶剂， 以20%的产率得到(1-(ferrocenylethynyl)-4-ethynylbenzenyl)-acridine
  参考文献：
  名称：

  Synthesis and characterization of ferrocenyl-acridine dyads and their multiresponse to proton and metal cations

  摘要：

  Two new pi-conjugated linked ferrocenyl-acridine dyads, (9-ethynylferrocenyl) acridine (3a) and (1-(ferrocenylethynyl)-4-ethynylbenzenyl)-acridine (3b), have been synthesized and investigated. UV-Vis spectroscopic and electrochemical studies reveal that 3a offers stronger electronic communication between terminal subunits than the extended system 3b, as shown by a stronger and lower-energy metal-toligand charge transfer (MLCT) transition and a more positive redox potential. Both of 3a and 3b show multiresponse to protons and selected metal ions (M = Zn2+, Pb2+, Hg2+, Fe3+, Cr3+), with a MLCT transition shift to the lower-energy, a redox potential shift to anode, and a luminescence increasing. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.02.013