MoCl(CO)2(1,10-phenanthroline)(η(3)-CH2C(COS-n-Bu)C=CH2) | 186651-80-9

• 英文名称: MoCl(CO)2(1,10-phenanthroline)(η(3)-CH2C(COS-n-Bu)C=CH2)
• CAS: 186651-80-9
• 化学式: C₂₃H₂₁ClMoN₂O₃S
• 分子量: 536.89
• InChiKey: XMYYLPAOYFPAOW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  MoCl(CO)2(1,10-phenanthroline)(η(3)-CH2C(COCl)C=CH2) 、 丁硫醇 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以70%的产率得到MoCl(CO)2(1,10-phenanthroline)(η(3)-CH2C(COS-n-Bu)C=CH2)
  参考文献：
  名称：

  Synthesis and characterisation of monomeric and dimeric 2-substituted η3-bonded butadienyl complexes of molybdenum(II)

  摘要：

  Addition of excess thiol RSH (R = Et, Pr-n, Pr-i, (n)Bu or (i)Bu) to solutions of [MoCl(CO)(2)(eta(3)-CH2C(COCl)C=CH2)(phen)] (1) (phen = 1,10-phenanthroline) gave good yields of the complexes [MoCl(CO)(2)(eta(3)-CH2C(COSR)C=CH2)(phen)], containing a 2-substituted butadienyl ligand. On reaction of 1 with 1,2-ethanedithiol in 2:1 molar ratio under basic conditions, dimeric complexes were obtained containing two metal centres bridged by a pair of 2-substituted butadienyl groups linked by the dithiol unit. Analogous dimeric complexes containing linked amido eta(3)-butadienyl groups were isolated from a similar 2:1 reaction of 1 and diamines RHN(CH2)(2)NHR (R = H or Me). However, reactions involving 1 and mixed bifunctional reactants HA(CH2)(2)BH (A = NH, B = O, S or A = O, B = S) under the same conditions gave monomeric complexes exclusively, the less electonegative atom of the donor pair remaining unreacted.

  DOI：

  10.1016/s0022-328x(96)06450-9