(η(5):η(1)-C5H4(CH2)2NtBu)TiCl2 | 195384-10-2

• 英文名称: (η(5):η(1)-C5H4(CH2)2NtBu)TiCl2
• CAS: 195384-10-2
• 化学式: C₁₁H₁₇Cl₂NTi
• 分子量: 282.049
• InChiKey: PJWJZMKEKJTUDT-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  N-(2-cyclopenta-2,4-dien-1-ylethyl)-2-methylpropan-2-amine 、 四氯化钛 在 Et₃N 作用下， 以 甲苯 为溶剂， 以60%的产率得到(η(5):η(1)-C5H4(CH2)2NtBu)TiCl2
  参考文献：
  名称：

  Titanium Dichloro, Bis(carbyl), Aryne, and Alkylidene Complexes Stabilized by Linked Cyclopentadienyl−Amido Auxiliary Ligands

  摘要：

  Thermal decomposition of the carbyl compounds {C5H4(CH2)(2)NR}TiR'(2) proceeds through alpha- and beta-H elimination to give stable aryne, alkylidene, and olefin. complexes in the presence of PMe3. Reaction of the dibenzyl compound {C5H4(CH2)(2)N-t-Bu}Ti(CH2Ph)(2) with B(C6F5)(3) gives the cationic [{C5H4(CH2)(2)N-t-Bu}TiCH2Ph](+), which is an active catalyst for the polymerization of ethene and propene.

  DOI：

  10.1021/om970472v