fac-[Mo(CO)3(CH3C(CH2TeCH3)3)] | 301664-53-9

• 英文名称: fac-[Mo(CO)3(CH3C(CH2TeCH3)3)]
• CAS: 301664-53-9
• 化学式: C₁₁H₁₈MoO₃Te₃
• 分子量: 677.002
• InChiKey: VBBMICNLLBONKF-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  2-Methyl-1,3-bis-methyltellanyl-2-methyltellanylmethyl-propane 、 molybdenum hexacarbonyl 以 乙腈 为溶剂， 以45%的产率得到fac-[Mo(CO)3(CH3C(CH2TeCH3)3)]
  参考文献：
  名称：

  Synthesis and spectroscopic characterisation of tritelluroether, triselenoether, and trithioether complexes of Cr(0), Mo(0) and W(0)

  摘要：

  The complexes fac-[M(CO)(3)L-3] (M = Mo or W, L-3 = MeC(CH2SMe)(3), MeC(CH2SeMe)(3) or MeC(CH2TeMe)(3)) have been prepared from [M(CO)(3)(MeCN)(3)] and characterised by analysis, FAB mass spectrometry, IR, H-1, C-13{H-1}, Se-77, Te-125 and Mo-95 NMR spectroscopies. The complexes are prone to decomposition in solution into tetracarbonyls, and attempts to isolate [Cr(CO)(3)L-3] have been unsuccessful. The complexes cis-[Cr(CO)(4){eta(2)-MeC(CH2SMe)(3)}], cis-[Mo(CO)(4)(eta(2)-MeC(CH2SeMe)(3)}] and the robust [M(CO)(4)(S-3)] (M = Cr, Mo or W, S-3 = 1,4,7-trithiacyclononane or 1,4,7-trithiacyclodecane) have been similarly characterised. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00425-3