[Ni(L)Cl₂] | 1421470-75-8

• 英文名称: [Ni(L)Cl₂]
• CAS: 1421470-75-8
• 化学式: C₂₈H₁₆Cl₂N₄NiO₄
• 分子量: 602.055
• InChiKey: MUHVMZRRICBWHL-UHFFFAOYSA-H

反应信息

• 作为产物：
  描述：

  nickel dichloride 、 1,4,9,12-tetraazacyclo-2,3,6,7,10,11,14,15-tetrabenzo-cetanan-5,8,13,16-tetraone 以 乙醇 为溶剂， 以67%的产率得到[Ni(L)Cl₂]
  参考文献：
  名称：

  Synthesis, spectroscopic characterization, molecular modeling and antimicrobial activities of Mn(II), Co(II), Ni(II), Cu(II) complexes containing the tetradentate aza Schiff base ligand

  摘要：

  Mn(II), Co(II), Ni(II), and Cu(II) complexes with a tetradentate macrocyclic ligand [1.2.5.6tetraoxo-3,4,7,8tetraaza-(1,2,3,4,5,6,7,8)tetrabenzene(L)] were synthesized and characterized by elemental analysis, molar conductance measurements, mass, nmr, is., electronic and e.p.r. spectral studies. All the complexes are non electrolytes in nature and may be formulated as [M(L)X-2] [where, M = Mn(II), Co(II), Ni(II), Cu(II) and X = Cl-, CH3COO-]. On the basis of i.r., electronic and e.p.r. spectral studies a distorted octahedral geometry has been assigned for all complexes. The antimicrobial activities and LD50 values of the ligand and its complexes, as growth inhibiting agents, have been screened in vitro against two different species of bacteria and plant pathogenic fungi. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2012.10.065