The cluster [Os3(CO)10(µ-L)](L = Ph2PC5H4N)(X-ray structure reported), containing the diaxially coordinated 2-pyridyldiphenylphosphine bridge, undergoes rapid transfer of the pyridine between two metal atoms while the phosphorus atom remains firmly coordinated to the third.
该簇[Os3(CO)10(µ-L)](L = Ph2PC5H4N)(已报告X射线结构)包含了双轴配位的2-
吡啶基
二苯基膦桥,在两个
金属原子之间迅速转移
吡啶,而
磷原子则牢固地配位于第三个
金属原子上。