{Pt(C2H4)2(P i-Pr3)} | 112834-80-7

• 英文名称: {Pt(C2H4)2(P i-Pr3)}
• CAS: 112834-80-7
• 化学式: C₁₃H₂₉PPt
• 分子量: 411.427
• InChiKey: WLGPQSOLTZVVAW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {Pt(C2H4)2(P i-Pr3)} 、 {W(CSiPh3)(CO)2(η-C5H5)} 生成 {WPt(μ-CSiPh3)(μ-CO)(CO)(P i-Pr3)(η-C5H5)}
  参考文献：
  名称：

  Compounds with platinum-molybdenum or -tungsten bonds derived from the alkylidyne metal complexes [M(CR)(CO)2(η-C5H5)] (M = Mo OR W; R = C6H4Me-4 OR C6H3Me2-2,6)

  摘要：

  DOI：

  10.1016/s0277-5387(00)81254-1
• 作为产物：
  描述：

  bis(cycloocta-1,5-diene)platinum(0) 、 三异丙基膦 以 Petroleum ether 为溶剂， 生成 {Pt(C2H4)2(P i-Pr3)}
  参考文献：
  名称：

  Compounds with platinum-molybdenum or -tungsten bonds derived from the alkylidyne metal complexes [M(CR)(CO)2(η-C5H5)] (M = Mo OR W; R = C6H4Me-4 OR C6H3Me2-2,6)

  摘要：

  DOI：

  10.1016/s0277-5387(00)81254-1

文献信息

• Ruthenium-platinum carbonyl cluster complexes with bridging methylene, methylidyne, and carbido ligands; crystal structures of the compounds [Ru2Pt(μ-CH2)(μ-CO)(CO)2{P(cyclo-C6H11)3}(η-C5H5)2], [Ru2Pt2(μ-H)(μ4-CH)(μ-CO)(CO)2(PPr3i)2(η-C5H5)2], and [Ru2Pt2(μ-H)2(μ4-C)(μ-CO)2(PPr3i)2(η-C5H5)2]
  作者：David L. Davies、John C. Jeffery、Daniel Miguel、Paul Sherwood、F.Gordon A. Stone

  DOI：10.1016/0022-328x(90)85148-r

  日期：1990.2

  [Ru2Pt(μ-CH2)(μ-CO)(CO)2P(cyclo-C6H11)3}(η-C5H5)2], [Ru2Pt2(μ-H)(μ4-CH)(μ-CO)(CO)2(PPr3i)2(η-C5H5)2], and [Ru2Pt2(μ-H)2(μ4-C)(μ-CO)2(PPr3i)2(η-C5H5)2] have been established by X-ray diffraction. The first compound has a structure based on an Ru2Pt triangle, with one RuPt bond bridged by a methylene group and the other by a carbonyl ligand. The ring in the second complex has a CO group bridging the PtPt bond and a

  的二钌化合物的[Ru 2（μ-CH 2）（μ-CO）（CO）（L）（η-C 5 H ^ 5）2 ]（L = CO或NCMe）与铂的试剂在温和条件[PT下反应（C 2 H ^ 4）2（PR 3）]（R =环-C 6 H ^ 11或Pr我），得到三和四核簇化合物的[Ru 2的PT（μ-CH 2）（μ-CO） （CO）2（PR 3）（η-C 5 H ^ 5）2 ]，[孺2的PT 2（μ-H）（μ 4-CH）（μ-CO）（CO）2（PR 3）2（η-C 5 H ^ 5）2 ]和[孺2的PT 2（μ-H）2（μ 4 -C）（μ-CO ）2（PR 3）2（η-C 5 H ^ 5）2 ]。该复合物的结构的[Ru 2的PT（μ-CH 2）（μ-CO）（CO）2 P（环-C 6 H ^ 11）3 }（η-C 5 H ^ 5）2 ]，[茹2的PT 2（μ-H）（μ 4 -CH）（μ-CO）（CO）2（PPR
• Transformations of µ-methylene-diruthenium complexes into tetranuclear metal clusters with µ₄-methylidyne and µ₄-carbido groups: X-ray crystal structures of [Ru₂Pt₂(µ-H)(µ₄-CH)(µ-CO)(CO)₂(PPrⁱ₃)₂(η-C₅H₅)₂] and [Ru₂Pt₂(µ-H)₂(µ₄-C)(µ-CO)₂(PPrⁱ₃)₂(η-C₅H₅)₂]
  作者：David L. Davies、John C. Jeffery、Daniel Miguel、Paul Sherwood、F. Gordon A. Stone

  DOI：10.1039/c39870000454

  日期：——

  The diruthenium compounds [Ru2(µ-CH2)(µ-CO)(CO)(L)(η-C5H5)2](L = CO or NCMe) react under mild conditions with the platinum complexes [Pt(C2H4)2(PR3)](R = cyclo-C6H11 or Pri) to afford tri- and tetranuclear metal compounds [Ru2Pt(µ-CH2)(µ-CO)(CO)2(PR3)(η-C 5H5)2], [Ru2Pt2(µ-H)(µ4-CH)(µ-CO)(CO)2(PR3)2(η-C5H5)2], and [Ru2Pt2(µ-H)2(µ4-C)(µ-CO)2(PR3)2(η-C5H5)2]; the species [Ru2Pt2(µ-H)(µ4-CH)(µ-CO)(CO)2(PPri3)2(η-C5H5)2] and [Ru2Pt2(µ-H)2(µ4-C)(µ-CO)2(PPri3)2(η-C5H5)2] have been structurally characterised by X-ray diffraction.

  在温和条件下，二钌化合物[Ru2(µ-CH2)(µ-CO)(CO)(L)(δ--C5H5)2](L = CO 或 NCMe)与铂配合物[Pt(C2H4)2(PR3)](R = cyclo-C6H11 或 Pri）发生反应，生成三核和四核金属化合物 [Ru2Pt(µ- )(µ-CO)(CO)2(PR3)(δ--C 5H5)2]、[Ru2Pt2(µ-H)(µ4-CH)(µ-CO)(CO)2(PR3)2(η- )2], and [Ru2Pt2(µ-H)2(µ4-C)(µ-CO)2(PR3)2(η- )2];用 X 射线衍射法确定了[Ru2Pt2(µ-H)(µ4-CH)(µ-CO)(CO)2(PPri3)2(δ-- )2]和[Ru2Pt2(µ-H)2(µ4-C)(µ-CO)2(PPri3)2(δ-- )2]这两种物质的结构特征。