| 220447-37-0

• CAS: 220447-37-0
• 化学式: C₆₈H₅₃Au₃F₅P₄*ClO₄
• 分子量: 1779.41
• InChiKey: ABBSDVAIYHAIHV-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  gold (acetylacetonato) triphenylphosphane 、 以 二氯甲烷 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Two alternatives for the synthesis of non-cyclic phosphino-methanide derivatives of gold

  摘要：

  The reaction of phosphine-phosphonium derivatives, such as [AuX(PPh2CH2PPh2Me)]ClO4 or [Au(C6F5)(3)(PPh2CH2PPh2Me)]ClO4, or non-cyclic bis(diphenylphosphino)methane-bridging complexes, as [Au(C6F5)(2)X(PPh2CH2PPh2)Au(C6F5)] (X=Cl, C6F5) or [AU(C6F5)(PPh2CH2PPh2)AU(C6F5)], with acetylacetonate derivatives or gold(I) compounds leads to the synthesis of non-cyclic methanide gold complexes of the types [AuX{PPh2C(AuPPh3)(2)PPh2Me}]ClO4, [AU(C6F5)(2)X{PPh2CH(AuPPh3)PPh2Me}]ClO4, [Au(C6F5)(3){PPh2CH-(AuPPh3)PPh2}Au(C6F5)], [N(PPh3)(2)][Au(C6F5)(3){PPh2CH-(AuX)PPh2}Au(C6F5)] or [N(PPh3)(2)][{Au(C6F5)(3)(PPh2CH2PPh2)-Au(C6F5)}(2)Au]. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00181-8