(2,4,6-trimethyl-(di-2-pyridylmethylene)aniline)dichloropalladium(II) | 1233324-27-0

• 英文名称: (2,4,6-trimethyl-(di-2-pyridylmethylene)aniline)dichloropalladium(II)
• CAS: 1233324-27-0
• 化学式: C₂₀H₁₉Cl₂N₃Pd
• 分子量: 478.717
• InChiKey: OHAGSGFFGFASER-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cis-dichlorobis(benzonitrile)palladium(II) 、 2,4,6-trimethyl(di-2-pyridylmethylene)aniline 以 二氯甲烷 为溶剂， 以98%的产率得到(2,4,6-trimethyl-(di-2-pyridylmethylene)aniline)dichloropalladium(II)
  参考文献：
  名称：

  Synthesis, characterization, and applications of novel di-2-pyridyl imine ligands

  摘要：

  Two novel di-2-pyridyl imines, 2,4,6-trimethyl-(di-2-pyridyl methylene)aniline (1) and 2,6-di-isopropyl-(di-2-pyridyl methylene)aniline (2), were prepared through condensation reactions between 2,2'-dipyridyl ketone and 2,4,6-trimethylaniline and 2,6-di-isopropylaniline. They reacted readily with bis(benzonitrile)dichloropalladium(II) to afford palladium imine complexes. The crystal structure of the palladium complex (3) bearing the 2,4,6-trimethyl-(di-2-pyridylmethylene)aniline ligand revealed coordination of a pyridyl group and an imine group to the metal center. The novel ligands were successfully employed in the Suzuki coupling reaction of p-bromoanisole and phenylboronic acid. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2009.10.013