| 244187-73-3

• CAS: 244187-73-3
• 化学式: BF₄*C₃₅H₃₇O₃P₂Ru
• 分子量: 755.499
• InChiKey: RPJXSWWBBPKXLE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (η5-pentamethylcyclopentadienyl)ruthenium(II)chloro[bis(diphenylphosphanyl)methane] 、 双氧水 、 四苯硼钠 以 氘代丙酮 、 水 为溶剂， 生成
  参考文献：
  名称：

  Dioxygen Complexes from the Reactions of [Cp*RuH₂(PP)]⁺ (PP = dppm, dppe) with Air

  摘要：

  Exposure of [Cp*RuH2(dppm)]BF4 in acetone or methanol to air produced a mixture of [Cp*Ru(O-2)(dppm)]BF4 and [Cp*Ru(O-2)(Ph2PCH2P(O)Ph-2)]BF4. Reaction of Cp*RuCl(dppm) with NaBPh4 in methanol in air produced the dioxygen complex [Cp*Ru(O-2)(dppm)]BPh4, which has been characterized by X-ray diffraction. Reaction of Cp*RuCl(dppm) with H2O2 in the presence of NaBPh4 in air produced [Cp*Ru(O-2)(Ph2PCH2P(O)Ph-2)]BPh4 and PH2P(O)CH2P(O)PPh2. Reaction of [Cp*RuH2(dppe)]BF4 in acetone or methanol with air also produced a mixture of [Cp*Ru(O-2)(dppe)]BF4 and [Cp*Ru(O-2)(Ph2PCH2CH2P(O)Ph-2)]BF4.

  DOI：

  10.1021/om990317b