trichloroaquabis(tetrahydrofuran)vanadium(III) | 172800-60-1

• 英文名称: trichloroaquabis(tetrahydrofuran)vanadium(III)
• CAS: 172800-60-1
• 化学式: C₈H₁₈Cl₃O₃V
• 分子量: 319.53
• InChiKey: MUKGXSZGHGEJLG-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  水 、 mer-VCl₃(tetrahydrofuran)3 以 二氯甲烷 为溶剂， 生成 trichloroaquabis(tetrahydrofuran)vanadium(III) 、
  参考文献：
  名称：

  The crystal structures and properties of [VCL3(THF)2(H2O] and [VCl3(THF)2(H2O)]·THF

  摘要：

  The structure of the products formed between [mer-VCl3(THF)(3)] and water in tetrahydrofuran (THF) or dichloromethane were investigated. Two different crystalline species were isolated: [VCl3(THF)(2)(H2O)] (1) and [VCl3(THF)(2)(H2O)]. THF (2). Their structures were determined by means of X-ray analysis. In both compounds the vanadium (III) ions are in a distorted octahedral environment surrounded by three mer-chlorine atoms, two trans-situated THF molecules and a water molecule.

  DOI：

  10.1016/0277-5387(95)00286-2