(cyclohexylphosphane)(methylcyclopentadienyl)molybdenium tetrachloride | 191542-23-1

• 英文名称: (cyclohexylphosphane)(methylcyclopentadienyl)molybdenium tetrachloride
• CAS: 191542-23-1
• 化学式: C₁₂H₂₀Cl₄MoP
• 分子量: 433.017
• InChiKey: ITXJILKZJPUWAC-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (acetonitrile)(methylcyclopentadienyl)molybdenum tetrachloride 、 环已基膦 以 甲苯 为溶剂， 以98%的产率得到(cyclohexylphosphane)(methylcyclopentadienyl)molybdenium tetrachloride
  参考文献：
  名称：

  Organometallic Molybdenum(V) Complexes with Promary Phosphane Ligands — Syntheses, Spectroscopic Properties, and Crystal Structures of [Cp′MoCl ₄ (PH ₂ R)] (R=2,4,6‐Pr ⁱ ₃ C ₆ H ₂ , Cyclohexyl, Cp′=C ₅ H ₄ Me)

  摘要：

  Abstract[Cp′MoCl4(CH3CN) (Cp′=C5H4Me) react with 2,4,6‐triisopropylphenylphosphane or cyclohexylphosphane to give the phosphane complexes [Cp′MoCl4(PH2R)] [R=2,4,6‐Pri3C6H2 (1)]. 1 and 2, were characterized spectroscopically (IR, MS) and by crystal structure determinations. EPR investigations in liquid and frozen solution confirmed the presence of Mo(V) species and the data were used to analyze the spin‐density distribution in the first coordination sphere.

  DOI：

  10.1002/cber.19971300621