2,2-difluoro-4-methyl-5,7-diphenyl-2,7-dihydro-2l4,3l3-[1,3,2]dioxaborinino[4,5-c]pyrazole | 1239677-15-6

• 英文名称: 2,2-difluoro-4-methyl-5,7-diphenyl-2,7-dihydro-2l4,3l3-[1,3,2]dioxaborinino[4,5-c]pyrazole
• CAS: 1239677-15-6
• 化学式: C₁₇H₁₃BF₂N₂O₂
• 分子量: 326.11
• InChiKey: LKQRMOGRDBJTIK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-acetyl-5-hydroxy-1,3-diphenyl-1H-pyrazole 在 三氟化硼乙醚 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以75%的产率得到2,2-difluoro-4-methyl-5,7-diphenyl-2,7-dihydro-2l4,3l3-[1,3,2]dioxaborinino[4,5-c]pyrazole
  参考文献：
  名称：

  Photoluminescence properties of new BF2 complexes with pyrazolone ligands: Dependence on volume and electronic effect of substituents

  摘要：

  Novel fluorine-boron complexes with donor-acceptor architecture in which pyrazoline-1,3-diones were chosen as electron donors have been synthesized and well characterized. Correlation of the luminescence properties of the complex 2c and its crystal structures was discussed. Well-ordered molecular packing in the crystal results in strong charge transfer interactions characterized by long excited-state lifetime. These fluorine-boron complexes show photophysical properties highly dependent on the solvent polarity and aggregation states. The substituents on the pyrazoline were found to have a significant impact on the solid-state luminescent properties. As a result, some significant differences in charge transfer modes were observed in the solid state among these complexes. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2010.05.006