| 375390-08-2

• CAS: 375390-08-2
• 化学式: C₅₄H₄₆FP₂Ru*F₆Sb
• 分子量: 1112.72
• InChiKey: UCKWZVSGRNCWBC-UHFFFAOYSA-H

反应信息

• 作为产物：
  描述：

  [Ru(rac-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(p-cymene)][SbF6]2*H2O 、 四丁基二氟三苯硅酸铵 以 二氯甲烷-D2 为溶剂， 生成
  参考文献：
  名称：

  Binap and MeO-Biphep complexes of Ru(II). Dicationic ligands as 6e donors. Unexpected cyclometallation in connection with P—C bond breaking

  摘要：

  A series of cationic and dicationic Ru-arene complexes with Binap (1a) and MeO-Biphep (1b) have been prepared. C-13 NMR studies are shown to be useful in connection with recognising the 6e-bonding mode of 1a and 1b in the dications [Ru(1a or 1b)(eta (6)-arene)](SbF6)(2) (8,9). Reaction of 8,9 with: (a) (Bu4N)(Ph3SiF2) leads to a cyclometallated product which arises via P-C bond breaking and P-F bond making; (b) methanol provides a straightforward synthesis of the corresponding hydrides. C-13 NMR p-cymene chemical shifts are reported.

  DOI：

  10.1139/cjc-79-5-6-693