[Zn(2-methanol-6-methylpyridine(-H))2][Zn(C6H4(NCHC6H2O(tBu)2)2)]2 | 1006592-05-7

• 英文名称: [Zn(2-methanol-6-methylpyridine(-H))2][Zn(C6H4(NCHC6H2O(tBu)2)2)]2
• CAS: 1006592-05-7
• 化学式: C₈₆H₁₀₈N₆O₆Zn₃
• 分子量: 1518.01
• InChiKey: SNDIBBOUJQZHPW-KXHMDYAXSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  6-甲基-2-吡啶基甲醇 、 (N,N'-phenylenebis(3,5-di-tert-butylsalicylideneimine))zinc 以 not given 为溶剂， 生成 [Zn(2-methanol-6-methylpyridine(-H))2][Zn(C6H4(NCHC6H2O(tBu)2)2)]2
  参考文献：
  名称：

  Creation of a Nonsymmetric Dimethanolpyridine Ligand:  A Rare Zn(salphen) Template Effect

  摘要：

  An interesting reversible, templated synthesis of unsymmetrical pyridine-ligated Zn complexes has been observed in solution and solid-state phases when Zn(salphen) complexes are reacted with methanol-substituted pyridine substrates. The X-ray molecular structure of an unusual Zn-3 supramolecular assembly is reported, in which the central Zn atom is embedded in a distorted octahedral geometry and each of the single anionic 0 atoms of the pyridine groups coordinates to a Zn(salphen) unit.

  DOI：

  10.1021/ic702225h