[Cu(2-(N-tosylamino)benzaldehyde 1-phthalazinylhydrazone(-H))(CH3OH)Cl] | 1323979-63-0

• 英文名称: [Cu(2-(N-tosylamino)benzaldehyde 1-phthalazinylhydrazone(-H))(CH3OH)Cl]
• CAS: 1323979-63-0
• 化学式: C₂₃H₂₂ClCuN₅O₃S
• 分子量: 547.524
• InChiKey: RANGENRPZVRAAG-VWIUBBDFSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 2-(N-tosylamino)benzaldehyde 1-phthalazinylhydrazone 、 copper dichloride 以 甲醇 为溶剂， 生成 [Cu(2-(N-tosylamino)benzaldehyde 1-phthalazinylhydrazone(-H))(CH3OH)Cl]
  参考文献：
  名称：

  Transition metal complexes with 2-(N-tosylamino)benzaldehyde 1-phthalazinylhydrazone

  摘要：

  2-(N-Tosylamino)benzaldehyde 1-phthalazinylhydrazone (H2L) and its complexes with Cu(II), Ni(II), and Mn(II) were obtained. The acid-basic properties of the hydrazone were studied using potentiometry and spectrophotometry. The experimental data were compared with the results of quantum-chemical DFT calculations. The structure of the binuclear complex [Cu2L2] was determined using X-ray diffraction. The broken symmetry approach was used to calculate the exchange coupling constant of the copper ions.

  DOI：

  10.1134/s1070328411060078