12-(ferrocenylcarbonyloxy)dodecane thiol | 146056-19-1

• 英文名称: 12-(ferrocenylcarbonyloxy)dodecane thiol
• CAS: 146056-19-1
• 化学式: C₂₃H₃₄FeO₂S
• 分子量: 430.435
• InChiKey: CJPOKUQUCRSAFY-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (ferrocenylcarbonyloxy)dodecyl bromide 、 硫脲 以 乙醇 为溶剂， 生成 12-(ferrocenylcarbonyloxy)dodecane thiol
  参考文献：
  名称：

  The Nature of Electronic Coupling between Ferrocene and Gold through Alkanethiolate Monolayers on Electrodes:  The Importance of Chain Composition, Interchain Coupling, and Quantum Interference

  摘要：

  Cyclic voltammetry was used to measure electron-transfer rate constants of self-assembled mixed monolayers. on gold electrodes formed by coadsorption of a redox-active ferrocene-based alkanethiol [(eta (C5H5)-C-5)Fe(eta (C5H4)-C-5)-. CO2(CH2)(5)X(CH2)(6)SH, where X = -CH2- or -O-] and a diluent alkanethiol [CH3(CH2)(4)Y(CH2)(6)SH, where Y = -CH2- or -O-]. The replacement of a methylene link by an ether link in the redox-active component leads to a significant reduction in the rate of electron transfer and results from a decrease in the electronic coupling through the chain. The corresponding replacement in the diluent leads to a smaller, but measurable, decrease in rate constant-suggesting that intermolecular electronic coupling pathways also contribute to the electron transfer.

  DOI：

  10.1021/jp0105140