2,6-dibromo-4,4-difluoro-8-(4-((2-hydroxybenzylidene)amino)phenyl)-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene | 1449134-43-3

• 英文名称: 2,6-dibromo-4,4-difluoro-8-(4-((2-hydroxybenzylidene)amino)phenyl)-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene
• CAS: 1449134-43-3
• 化学式: C₂₆H₂₂BBr₂F₂N₃O
• 分子量: 601.096
• InChiKey: KAMMXWGLFLIDIJ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  10-{4-[(2-Hydroxybenzylidene)amino]phenyl}-5,5-difluoro-1,3,7,9-tetramethyl-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide 在 N-溴代丁二酰亚胺(NBS) 作用下， 反应 0.08h， 以81%的产率得到2,6-dibromo-4,4-difluoro-8-(4-((2-hydroxybenzylidene)amino)phenyl)-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene
  参考文献：
  名称：

  Regioselective 2,6-dihalogenation of BODIPYs in 1,1,1,3,3,3-hexafluoro-2-propanol and preparation of novel meso-alkyl polymeric BODIPY dyes

  摘要：

  在六氟异丙醇（HFIP）中，对BODIPYs进行区域选择性的2,6-卤化反应，在不到5分钟内获得了产物。卤化的BODIPYs经过Pd催化的交叉偶联反应形成了新型的meso-烷基聚合物BODIPY染料。

  DOI：

  10.1039/c3ra41298a

文献信息

• Facile and environmentally friendly halogenation of BODIPYs in deep eutectic solvent
  作者：Liang Wang、Kai-qiang Zhu、Qun Chen、Ming-yang He

  DOI：10.1016/j.dyepig.2014.07.024

  日期：2015.1

  A deep eutectic solvent based on choline chloride and 1,1,1,3,3,3-hexafluoro-2-propanol was prepared. This deep eutectic solvent was used as the reaction medium for halogenation of boron dipyrromethene in the presence of N-halosuccinimide, which delivered the corresponding products in good to excellent yields (79-94%) in short reaction time (usually within 30 min). Moreover, this deep eutectic solvent could be easily prepared, recovered and reused for several runs without significant loss in the yields. (C) 2014 Elsevier Ltd. All rights reserved.