chlorobis(η5-indenyl)(P(Si(CH3)3P(N(CH(CH3)2)2)2-κP1) | 1374823-40-1

• 英文名称: chlorobis(η5-indenyl)(P(Si(CH3)3P(N(CH(CH3)2)2)2-κP1)
• CAS: 1374823-40-1
• 化学式: C₃₃H₅₁ClN₂P₂SiZr
• 分子量: 692.491
• InChiKey: DTHXDVCRBKXZBD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  chlorobis(η5-indenyl)(P(Si(CH3)3P(N(CH(CH3)2)2)2-κP1) 以 氘代苯 为溶剂， 以0%的产率得到chlorobis(η5-indenyl)(N(CH(CH3)2)2)
  参考文献：
  名称：

  π-Indenyl substituted zirconium compounds containing terminal bonded phosphanylphosphido ligands [Ind2Zr(Cl){(Me3Si)P–PR2-κP1}]. Synthesis, X-ray analysis and NMR studies

  摘要：

  Dichloro-bis(indenyl)zirconium(IV) reacts with lithium derivatives of diphosphanes R2P-P(SiMe3)Li (R = Bu-t, Et2N, (Pr2N)-Pr-i) to form complexes with terminal phosphanylphosphido ligands - [Ind(2)Zr(Cl){(PSiMe3)P-PR2-kappa P-1}]. These compounds are extremely sensitive towards moisture and oxygen. The solid state structures of these complexes were established by single crystal X-ray diffraction. The nitrogen bearing groups R (Et2N or (Pr2N)-Pr-i) significantly lengthen the P-P distances in the related complexes and change the geometry around the phosphido phosphorus in such a way that it becomes less planar. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.02.028
• 作为产物：
  描述：

  双茚基锆(VI)二氯化合物 、 ((i)Pr2N)2P-P(SiMe3)Li*2.6THF 以 甲苯 为溶剂， 以24%的产率得到chlorobis(η5-indenyl)(P(Si(CH3)3P(N(CH(CH3)2)2)2-κP1)
  参考文献：
  名称：

  π-Indenyl substituted zirconium compounds containing terminal bonded phosphanylphosphido ligands [Ind2Zr(Cl){(Me3Si)P–PR2-κP1}]. Synthesis, X-ray analysis and NMR studies

  摘要：

  Dichloro-bis(indenyl)zirconium(IV) reacts with lithium derivatives of diphosphanes R2P-P(SiMe3)Li (R = Bu-t, Et2N, (Pr2N)-Pr-i) to form complexes with terminal phosphanylphosphido ligands - [Ind(2)Zr(Cl){(PSiMe3)P-PR2-kappa P-1}]. These compounds are extremely sensitive towards moisture and oxygen. The solid state structures of these complexes were established by single crystal X-ray diffraction. The nitrogen bearing groups R (Et2N or (Pr2N)-Pr-i) significantly lengthen the P-P distances in the related complexes and change the geometry around the phosphido phosphorus in such a way that it becomes less planar. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.02.028