[(PdCl2)2(doxpy(CH2NMe2)2)] | 1167576-73-9

• 英文名称: [(PdCl2)2(doxpy(CH2NMe2)2)]
• CAS: 1167576-73-9
• 化学式: C₁₈H₂₄Cl₄N₄O₂Pd₂
• 分子量: 683.066
• InChiKey: VJGYSWZXOMZMSX-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  盐酸 、 doxpy(CH2NMe2)2 、 palladium diacetate 在 C₆H₅OLi 作用下， 以 二氯甲烷 为溶剂， 以85%的产率得到[(PdCl2)2(doxpy(CH2NMe2)2)]
  参考文献：
  名称：

  Binuclear Complexes of Bis-Chelating Ligands Based on [1,4]Dioxocino[6,5-b:7,8-b′]dipyridine Moieties

  摘要：

  Binucleating ligands based on a [1,4]dioxocino[6,5-b: 7,8 -b']dipyridine (doxpy) core were prepared and characterized. They all present two equal chelating moieties each one including one N, O, or S donor in addition to a pyridinic nitrogen. At least one d(8) ion (Pd-II or Pt-II) complex was prepared for each type of ligand. The stereochemical behavior of the ligands and the complexes, along with the cooperative catalytic ability of two Pd-II centers are discussed.

  DOI：

  10.1021/ic900239z