Synthesis, Structure, and Fluxionality of (μ-Diphenylsilylene)(fulvalene)tetracarbonyldirhenium Double Si−H Activation to the First Fulvalene Silylene Complex
摘要:
(Fulvalene)hexacarbonyldirhenium (1) furnishes the first silylene fulvalenedimetal complex 3 by double Si-H activation. The solid-state structure of the molecule was determined by X-ray analysis and its solution dynamics by (1)H NMR spectroscopy.