N,N'-di(p-tolyl)-N-thallium-benz(α-naphth)amidinium-N'-[2,3,4,5-tetra(methoxycarbonyl)cyclopentadien-1-yl]ide | 372519-06-7

• 英文名称: N,N'-di(p-tolyl)-N-thallium-benz(α-naphth)amidinium-N'-[2,3,4,5-tetra(methoxycarbonyl)cyclopentadien-1-yl]ide
• CAS: 372519-06-7
• 化学式: C₃₈H₃₃N₂O₈Tl
• 分子量: 850.072
• InChiKey: SZIJVTKSRQMVHJ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  N,N'-di(p-tolyl)-N-methoxycarbonyl-benz(α-naphth)amidinium-N'-[2,3,4,5-tetra(methoxycarbonyl)cyclopentadien-1-yl]ide 、 thallium(I) hydroxide 以 甲醇 为溶剂， 生成 N,N'-di(p-tolyl)-N-thallium-benz(α-naphth)amidinium-N'-[2,3,4,5-tetra(methoxycarbonyl)cyclopentadien-1-yl]ide
  参考文献：
  名称：

  摘要：

  The chiral thallium amidinium cyclopentadiene-N-ylide complexes [C-5(CO2Me)(4){ArNC(Ar ' )NAr}]Tl were synthesized and structurally characterized by X-ray diffraction analysis and NMR spectroscopy. In these complexes, an unusual mode of coordination of the thallium atom was found, viz., the thallium atom is coordinated by both the side-chain nitrogen atom (N-Tl, 2.833(6) Angstrom) and the pi system of the cyclopentadienyl ring (Tl-Cp, 2.887(4) Angstrom; eta (5)-bonding).

  DOI：

  10.1023/a:1011323629390