[Cu(benzoin (phthalazin-1-yl)hydrazone(-2H))]2 | 1210032-40-8

• 英文名称: [Cu(benzoin (phthalazin-1-yl)hydrazone(-2H))]2
• CAS: 1210032-40-8
• 化学式: C₄₄H₃₂Cu₂N₈O₂
• 分子量: 831.882
• InChiKey: HPYAWVQAEGUIIQ-GYQLWQNTSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper diacetate 、 benzoin (phthalazin-1-yl)hydrazone 以 甲醇 为溶剂， 生成 [Cu(benzoin (phthalazin-1-yl)hydrazone(-2H))]2
  参考文献：
  名称：

  Specificity of complex formation of benzoin (phthalazin-1-yl)hydrazone with copper(II) and nickel(II): Physicochemical study and quantum-chemical simulation

  摘要：

  Benzoin (phthalazin-1-yl)hydrazone and its complexes with copper(I), copper(II), and nickel(II) were synthesized. Acid-base properties of benzoin (phthalazin-1-yl)hydrazone were studied, and its ionization constants and energies of possible conformers were calculated by quantum-chemical methods. The structure of the isolated complexes was determined on the basis of their elemental compositions, IR spectra, and data of thermogravimetric, conductometric, and magnetochemical measurements. Copper(II) acetate with benzoin (phthalazin-1-yl)hydrazone forms dinuclear complex, nickel(II) acetate and chloride produce mononuclear octahedral complexes, and copper(II) halides give rise to copper(I) complexes with the oxidized hydrazone.

  DOI：

  10.1134/s1070363209040240