bis(phenyldimethylphosphine)molybdenum tetracarbonyl | 24554-47-0

• 英文名称: bis(phenyldimethylphosphine)molybdenum tetracarbonyl
• CAS: 24554-47-0
• 化学式: C₂₀H₂₂MoO₄P₂
• 分子量: 484.28
• InChiKey: CVIUPJGQVKPAII-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  sodium tetrahydroborate 、 二甲基苯基磷 、 molybdenum hexacarbonyl 以 乙醇 为溶剂， 生成 bis(phenyldimethylphosphine)molybdenum tetracarbonyl
  参考文献：
  名称：

  Complexes of molybdenum(III) and -(IV) with chloride and tertiary phosphine ligands; an omniumgatherum of new and old results

  摘要：

  The preparations and structures of four new mixed chloro-tertiary phosphine complexes 1,3-5 of molybdenum(III) are reported, as well as the structure of two previously known Mo-III complexes 2, 6 and the structure of an [MoCl6](2-) compound 7. These results are discussed along with data for other such compounds.

  DOI：

  10.1016/0277-5387(95)00096-b

文献信息

• Quadruply bonded tetramethyltetrakis(trialkylphosphine)dimolybdenum compounds: phosphine exchange kinetics, acetone formation with carbon monoxide and crystal structure of Mo2Me4(PMe3)4
  作者：Gregory S. Girolami、Vera V. Mainz、Richard A. Andersen、Sara H. Vollmer、Victor W. Day

  DOI：10.1021/ja00403a069

  日期：1981.7