| 68091-53-2

• CAS: 68091-53-2
• 化学式: AuCl₄*C₂₄H₂₀P
• 分子量: 678.175
• InChiKey: CUWHDLUMKNIJNK-UHFFFAOYSA-J

反应信息

• 作为反应物：
  描述：

  5-mercapto-1-methyltetrazole sodium salt hydrate 、 以 二氯甲烷 为溶剂， 以99%的产率得到tetraphenylphosphonium tetrakis(1-methyl-1,2,3,4,-tetrazole-5-thiolato-S)aurate(III) hemihydrate
  参考文献：
  名称：

  Tetraphenylphosphonium tetrakis(1-methyl-1,2,3,4-tetrazole-5-thiolato-S)aurate(III) hemihydate

  摘要：

  The tetraphenylphosphonium salt of tetrakis(1-methyl-1,2,3,4-tetrazole-5-thiolato)aurate(III) crystallizes as an H2O hemisolvate, (C24H20P)[Au(C2H3N4S)(4)]. 0.5H(2)O, in the monoclinic C2/c space group, with the Au atom situated on an inversion centre. The tetrazole rings are arranged almost orthogonally with respect to the square coordination sphere. Au-S-C angles of 106.2(1) and 107.1(1)degrees were found.

  DOI：

  10.1107/s0108270199004357