[Pt(4'-(1-naphthyl)-2,2:6',2''-terpyridine)(CCC6H5)][SbF6] | 874383-94-5

• 英文名称: [Pt(4'-(1-naphthyl)-2,2:6',2''-terpyridine)(CCC6H5)][SbF6]
• CAS: 874383-94-5
• 化学式: C₃₃H₂₂N₃Pt*F₆Sb
• 分子量: 891.378
• InChiKey: WAWZZDZYOUMJHY-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Pt(4'-(1-naphthyl)-2,2:6',2''-terpyridine)Cl][SbF6] 、 silver phenylacetylide 以 吡啶 为溶剂， 以73%的产率得到[Pt(4'-(1-naphthyl)-2,2:6',2''-terpyridine)(CCC6H5)][SbF6]
  参考文献：
  名称：

  Synthesis and luminescence properties of [Pt{4′-(Np1)-trpy}(CCPh)]SbF6 and [Pt{4′-(Np1)-trpy}{CC(CH2)2CH3}]SbF6 [4′-(Np1)-trpy=4′-(1-naphthyl)-2,2′:6′,2″-terpyridine]

  摘要：

  The synthesis and characterisation of [Pt{4'-(Npl)-trpy} (C&3bond; CPh)]SbF6 (1) and [Pt{4'-(Npl)-trpy} {C&3bond; C(CH2)(2)CH3}]SbF6 (2) [4'-(Npl)-trpy=4'-(1-naplitliyl)-2,2:6',2'-terpyridine] are described. Complexes 1 and 2 exhibit unimolecular (MLCT)-M-3 (MLCT = metal-to-ligand charge transfer) emission in acetonitrile and in a low concentration 77 K glass solution in butyronitrile. The high concentration glass emission as well as the emission in the solid state is from a (MMLCT)-M-3 (MMLCT, metal-metal-to-ligand charge transfer) excited state, reflecting the presence of d(z)(2)(Pt)-d(z)(2)(Pt) interactions in these media. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.06.085