di-μ-tert-butylimido-bis[(η-methylcyclopentadienyl)oxomolybdenum] (Mo-Mo) | 161336-39-6

• 英文名称: di-μ-tert-butylimido-bis[(η-methylcyclopentadienyl)oxomolybdenum] (Mo-Mo)
• CAS: 161336-39-6
• 化学式: C₂₀H₃₂Mo₂N₂O₂
• 分子量: 524.366
• InChiKey: RBXFVJKRWCREQV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (tert-butylimido)dichloro(η-methylcyclopentadienyl)molybdenum 、 lithium tert-butylamide 以 甲苯 为溶剂， 以8%的产率得到di-μ-tert-butylimido-bis[(η-methylcyclopentadienyl)oxomolybdenum] (Mo-Mo)
  参考文献：
  名称：

  η-Cyclopentadienylimido molybdenum chemistry: hydrido, alkyl and η-alkyl derivatives

  摘要：

  The following compounds have been prepared and characterized: [Mo(eta-C(5)H(4)R)Cl-3(NBu(t))] (R=H, Me or Pr-i). [{MoCl3(mu-Cl)(NBu(t))}(2)], cis- and trans-[{Mo(eta-C(5)H(4)Me)(NBu(t))(mu-NBu(t))}(2)], [{Mo(eta-C(5)H(4)Me)O(mu-NBu(t))}(2)], [Mo(eta-C(5)H(4)Me)(eta-C2H4)Me)(eta-C2H4(NBu(t))], [Mo(eta-C5H5)(eta-C2H4)Ph(NBu(t))], [Mo(eta-C(5)H(4)Me) (eta-C2H4)(H or D)(NBu(t))], [Mo(eta-C(5)H(4)Me)(PMe(3))Cl(NBu(t))], [Mo(eta-C(5)H(4)Me)(PMe(3))Me(NBu(t))], [Mo(eta-C(5)H(4)Me)(PMe(3))(2)(NBu(t))](+)A(-) (A = Cl or BF4). [Mo(eta-C(5)H(4)Me)(PMe(3)Ph)Cl(NBu(t))], isomers of [Mo(eta-C(5)H(4)R)(eta-C3H5) (NBUt)] (R = Me or Pr-i), and [Mo(mu-C5H4Me)(eta-C2H4)(sigma-C3H5)(NBu(t))]. The crystal structure of [{MoCl3(mu-Cl)(NBu(t))}(2)] has been determined. These compounds include the first or rare examples of combinations of ligands with the imido group, for example, imido eta 3-allyl derivatives.

  DOI：

  10.1039/dt9940002975