RuH(CO)(PPh3)(2,6-(Ph2PCH2)2C6H3) | 192751-57-8

• 英文名称: RuH(CO)(PPh3)(2,6-(Ph2PCH2)2C6H3)
• CAS: 192751-57-8
• 化学式: C₅₁H₄₃OP₃Ru
• 分子量: 865.893
• InChiKey: WZQKCCBTFCLMSI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四氟硼酸-二乙醚络合物 、 RuH(CO)(PPh3)(2,6-(Ph2PCH2)2C6H3) 以 二氯甲烷 为溶剂， 以76%的产率得到[Ru(CO)(PPh3)(2,6-(Ph2PCH2)2C6H3)]BF4
  参考文献：
  名称：

  Five- and six-coordinate ruthenium complexes with the tridentate orthometallated aryl bisphosphine ligand [2,6-(Ph2PCH2)2C6H3]−

  摘要：

  A series of ruthenium complexes with the orthometallated ligand [2,6-(Ph2PCH2)(2)C6H3](-) (PCP) was synthesized. Reaction of RuCl2(PPh3)(3) with 1,3-(Ph2PCH2)(2)C6H4 produced the coordinatively unsaturated complex RuCl(PPh3)(PCP), which was characterized by X-ray crystallography. Treatment of RuCl(PPh3)(PCP) with 4-phenylpyridine (pyph) yielded RuCl(pyph)(PPh3)(PCP). Treatment of RuCl(PPh3)(PCP) with PMe3 and CO generated RuCl(PMe3)(2)(PCP) and RuCl(CO)(2)(PCP) respectively. Reactions of RuCl(PPh3)(PCP) with NaH in THF and NaBH4 in methanol gave RuH(PPh3)(PCP) and RuH(CO)(PPh3)(PCP) respectively. The hydride complex RuH(PMe3),(PCP) was prepared by the reaction of RuCl(PMe3),(PCP) with NaBH4.

  DOI：

  10.1016/s0022-328x(96)06926-4
• 作为产物：
  描述：

  甲醇 、 [1,3-(Ph2PCH2)2C6H3-2-Ru(Cl)PPh3] 、 sodium tetrahydroborate 以 甲醇 为溶剂， 以87%的产率得到RuH(CO)(PPh3)(2,6-(Ph2PCH2)2C6H3)
  参考文献：
  名称：

  Five- and six-coordinate ruthenium complexes with the tridentate orthometallated aryl bisphosphine ligand [2,6-(Ph2PCH2)2C6H3]−

  摘要：

  A series of ruthenium complexes with the orthometallated ligand [2,6-(Ph2PCH2)(2)C6H3](-) (PCP) was synthesized. Reaction of RuCl2(PPh3)(3) with 1,3-(Ph2PCH2)(2)C6H4 produced the coordinatively unsaturated complex RuCl(PPh3)(PCP), which was characterized by X-ray crystallography. Treatment of RuCl(PPh3)(PCP) with 4-phenylpyridine (pyph) yielded RuCl(pyph)(PPh3)(PCP). Treatment of RuCl(PPh3)(PCP) with PMe3 and CO generated RuCl(PMe3)(2)(PCP) and RuCl(CO)(2)(PCP) respectively. Reactions of RuCl(PPh3)(PCP) with NaH in THF and NaBH4 in methanol gave RuH(PPh3)(PCP) and RuH(CO)(PPh3)(PCP) respectively. The hydride complex RuH(PMe3),(PCP) was prepared by the reaction of RuCl(PMe3),(PCP) with NaBH4.

  DOI：

  10.1016/s0022-328x(96)06926-4