σ-(Pt[1H-1-methyl-2-(2'-pyridinyl)-indolyl-C(3),N'](Bu(t)NC)Cl) | 310413-98-0

• 英文名称: σ-(Pt[1H-1-methyl-2-(2'-pyridinyl)-indolyl-C(3),N'](Bu(t)NC)Cl)
• CAS: 310413-98-0
• 化学式: C₁₉H₂₀ClN₃Pt
• 分子量: 520.921
• InChiKey: ITDJRTFZTNGAGF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  σ-(Pt[1H-1-methyl-2-(2'-pyridinyl)-indolyl-C(3),N'](DMSO)Cl) 、 异氰酸叔丁酯 以 二氯甲烷 为溶剂， 以51%的产率得到σ-(Pt[1H-1-methyl-2-(2'-pyridinyl)-indolyl-C(3),N'](Bu(t)NC)Cl)
  参考文献：
  名称：

  Carbene complexes of cycloplatinated 1H-indole-1-methyl-2-(2′-pyridine). The crystal and molecular structure of σ-{Pt[1H-indole-1-methyl-2-(2′-pyridinyl-C3,N′](DMSO)Cl} and of σ-{Pt[1H-indole-1-methyl-2-(2′-pyridinyl-C3,N′)][C(OCH2CH3)(CH2C6H5)]Cl}

  摘要：

  Reaction of 1-methyl-2-(2'-pyridinyl)-1H-indole (1) with PtCl2(DMSO)(2) (DMSO = dimethylsulfoxide) gave the cycloplatinated product 2; X-ray structure determination of 2 showed a metallation to platinum via the C3 carbon of the indole nucleus, which is chelated to the metal via the pyridine nitrogen atom. Compound 2 reacts with neutral ligands such as CO, Bu'NC, styrene and phenylacetylene, to give compounds 3-6 respectively, where DMSO is replaced by the neutral ligands. The phenylacetylene derivative 6 reacts with ethanol to give the carbene complex 7, whose X-ray structure has been determined. Related carbene complexes with other alcohols and other acetylenic derivatives have also been synthesised. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00343-0