[6,9-μ-(NHtBu)-5-Ph-arachno-5,10-C2B8H10] | 296230-01-8

• 英文名称: [6,9-μ-(NHtBu)-5-Ph-arachno-5,10-C2B8H10]
• CAS: 296230-01-8
• 化学式: C₁₂H₂₅B₈N
• 分子量: 269.825
• InChiKey: FNODCDDBBFTKOP-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  、 苯乙炔 以 甲苯 为溶剂， 以18%的产率得到[6,9-μ-(NHtBu)-5-Ph-arachno-5,10-C2B8H10]
  参考文献：
  名称：

  Polyhedral azadicarbaborane chemistry. The ‘converse’ synthesis of a small family of 6,9-(NHR)-bridged-arachno-5,10-dicarbadecaboranes

  摘要：

  Addition of PhC=CH to hypho-type species [(R'H2N)B8H11NHR] proceeds readily with the displacement of R'NH2 to give corresponding N-bridged arachno ten-vertex species [6,9-mu-(NHR)-5-Ph-arachno-5,10-C2B8H10] (15 - 34%), for which DFT structural and GIAO B-11 nuclear shielding calculations suggest the syn configurations that have the R and Ph groupings on the same side of the molecule. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00099-2