di-μ-isocyanato-bis[isocyanato(1,10-phenanthroline)copper(II)] | 177601-87-5

• 英文名称: di-μ-isocyanato-bis[isocyanato(1,10-phenanthroline)copper(II)]
• CAS: 177601-87-5
• 化学式: C₂₈H₁₆Cu₂N₈O₄
• 分子量: 655.578
• InChiKey: UWRIEQUZUIILJZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium cyanate 、 copper(II) choride dihydrate 、 邻菲罗啉 以 乙醇 、 水 为溶剂， 生成 di-μ-isocyanato-bis[isocyanato(1,10-phenanthroline)copper(II)]
  参考文献：
  名称：

  Di-μ-isocyanato-bis[isocyanato(1,10-phenanthroline)copper(II)]

  摘要：

  The structure of blue [Cu-2(NCO)(4)(C12H8N2)(2)] consists of [Cu(NCO)(2)(phen)] subunits (phen is 1,10-phenanthroline) in a distorted planar arrangement, the subunits existing in centrosymmetrically related pairs in the crystal packing. The subunits have a distorted four-coordinate square-planar arrangement of N atoms about the central Cu atom; pairs of these [Cu(NCO)(2)(phen)] subunits form dimers by interaction of the fifth position on each Cu center with an N atom of an isocyanate ligand of the associated subunit. The coordination around each Cu atom is best described as distorted square-pyramidal.

  DOI：

  10.1107/s0108270195016799