dichloro(hydroxy-methoxy-di(2-pyridyl)methane)copper(II) | 172755-83-8

• 英文名称: dichloro(hydroxy-methoxy-di(2-pyridyl)methane)copper(II)
• CAS: 172755-83-8
• 化学式: C₁₂H₁₂Cl₂CuN₂O₂
• 分子量: 350.691
• InChiKey: WDIIENCODXLGGP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-二吡啶基酮 、 copper dichloride 以 甲醇 为溶剂， 生成 dichloro(hydroxy-methoxy-di(2-pyridyl)methane)copper(II)
  参考文献：
  名称：

  Structure and spectra of dichloro(hydroxy-methoxy-di(2-pyridyl)methane)copper(II)

  摘要：

  The non-electrolyte dichloro(hydroxy-methoxy-di(2-pyridyl)methane)coper(II), resulting from the reaction of di(2-pyridyl)ketone and copper(II) chloride in methanol solution, was isolated and characterized and its structure was determined by X-ray diffraction. The pyridyl nitrogens and the chloride anions virtually form a basal plane in which lies the copper atom, while the oxygen of the methoxy group is in an apical position at a distance of 2.497(3)Angstrom. The nitrogenous base adopts the boat conformation with the pyridyl rings forming a dihedral angle of 108.72(14)degrees. The nearest interatomic copper distance of 3.940(3)Angstrom precludes copper-copper interactions, while the proximity of copper to the out-of-plane chlorine atoms [3.109(3)Angstrom] suggests weakly bound chloro-bridged dimers. Spectral changes indicate that protic molecules displace the methoxy group and water affords the corresponding 1,1-diol.

  DOI：

  10.1016/0277-5387(95)00258-t