[Cp(Cl)Al(μ-SEt)]2 | 849463-05-4

• 英文名称: [Cp(Cl)Al(μ-SEt)]2
• CAS: 849463-05-4
• 化学式: C₁₄H₂₀Al₂Cl₂S₂
• 分子量: 377.314
• InChiKey: CVDTZNBFHDZOSG-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  ethylthiolatodichloroaluminum 、 lithium cyclopentadienide 以 正己烷 为溶剂， 生成 [Cp(Cl)Al(μ-SEt)]2
  参考文献：
  名称：

  Cyclopentadienylaluminum thiolates – synthesis and structure

  摘要：

  The dicyclopentadienylaluminum thiolates [Cp2Al(mu-SR)](2), where R = Et (1),Pr-i (2), were obtained by reacting Cl2AlSR with CpNa at the molar ratio 1:2, respectively. Use of CpLi instead of CpNa at the same molar ratio of reagents leads to the formation of cyclopentadienyl(chloro)aluminum thiolates [Cp(C1)Al(mu-SR)](2), exclusively, where R = Et (3), Pr-i (4), Bu-i (5), and Bu-n (6). The compounds were characterized by H-1, C-13, and Al-27 NMR spectroscopy. The structures of the compounds 1 and 4 were determined by X-ray crystallography. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.10.057