rhodiumgold(carbonyl)(PPh3)2(η5-C2B9H11) | 130559-21-6

• 英文名称: rhodiumgold(carbonyl)(PPh3)2(η5-C2B9H11)
• CAS: 130559-21-6
• 化学式: C₃₉H₄₁AuB₉OP₂Rh
• 分子量: 984.872
• InChiKey: CIGXAGCRJAAYHI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  以 not given 为溶剂， 生成 rhodiumgold(carbonyl)(PPh3)2(η5-C2B9H11)
  参考文献：
  名称：

  (Carborane)rhodium-gold complexes

  摘要：

  Treatment of the reagent [NEt4][Rh(CO)(PPh3)(eta5-7,9-C2B9H11)] in CH2Cl2, in the presence of TlBF4, with half an equivalent of the digold compounds [Au2Cl2{mu-Ph2P(CH2)nPPh2}] (n = 2-6) affords the complexes [Rh2Au2{mu-Ph2P(CH2)nPPh2}(CO)2 (PPh3)2(eta5-7,9-C2B9H11)2]. The compounds [Rh2Au2{mu=Ph2P(CH2)nPPh2}(CO)2(PPh3)2 (eta5-7,8-C2B9H11)2] (n = 3 or 6) have similarly been prepared. Reactions between the digold complexes [Au2Cl2(mu-Z or E-Ph2PCH=CHPPh2)] and the salts [NEt4][Rh(CO)(PPh3)(eta5-7,n-C2B9H11)] (n = 8 or 9) give the four isomeric dirhodium-digold complexes [Rh2Au2(mu-Z or E-Ph2PCH=CHPPh2)(CO)2(PPh3)2(eta5-7,n-C2B9H11)2]. The NMR data for the new compounds are reported and discussed in terms of the formulations proposed.

  DOI：

  10.1016/s0277-5387(00)83584-6

文献信息

• Carr, Nicholas; Gimeno, M. Concepcion; Goldberg, Justin E., Journal of the Chemical Society, Dalton Transactions
  作者：Carr, Nicholas、Gimeno, M. Concepcion、Goldberg, Justin E.、Pilotti, Massimino U.、Stone, F. Gordon A.、Topaloglu, Isil

  DOI：——

  日期：——