| 65892-11-7

• CAS: 65892-11-7
• 化学式: C₁₆H₅NO₁₁Os₃
• 分子量: 957.816
• InChiKey: OZQPSAIYTLWPAJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 pyridine 作用下， 以 正辛烷 为溶剂， 生成 (μ-H)Os3(μ-NC5H4)(CO)10
  参考文献：
  名称：

  吸附在铂（111）上的吡啶的电子能量损失和热解吸光谱

  摘要：

  DOI：

  10.1021/j100280a088
• 作为产物：
  描述：

  十二羰基三锇 在 NC₅H₅ 、 trimethylamine oxide 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  吸附在铂（111）上的吡啶的电子能量损失和热解吸光谱

  摘要：

  DOI：

  10.1021/j100280a088

文献信息

• Photochemistry of [Ru3(CO)12] with nitrogen heterocycles
  作者：Nicholas E. Leadbeater、Jack Lewis、Paul R. Raithby、Gregory N. Ward

  DOI：10.1039/a702099f

  日期：——

  The photochemistry of [M 3 (CO) 12 ] (M = Ru 1a or Os 1b) with nitrogen heterocycles has been studied. In all cases photolysis leads to photosubstitution products, the heterocycles inhibiting the photofragmentation pathway. With pyridine (py) 1a formed the orthometallated complex [Ru 3 H(CO) 10 (C 5 H 4 N)] 2a. With osmium, the simple substitution product [Os 3 (CO) 11 (py)] 3b can be isolated. With 2-methylpyridine (mpy) [Ru 3 H(CO) 10 (2-MeC 5 H 3 N)] 5a and [Os 3 (CO) 11 (mpy)] 6b were formed from 1a and 1b respectively. With 2,6-dimethylpyridine no net photoreaction was observed. Photolysis of 1a and 1b with 2,2′-bipyridine led to the formation of [M 3 (CO) 10 (bipy)] (M = Ru 7a and Os 7b). The molecular structure of 7b has been obtained by single-crystal X-ray diffraction studies. Photolysis of 1a and 1b with pyridazine (pydz) led to the substituted products [M 3 (CO) 10 (pydz)] (M = Ru 8a or Os 8b).

  研究了[M 3 (CO) 12 ]（M = Ru 1a 或 Os 1b）与氮杂环的光化学作用。在所有情况下，光解都会导致光置换产物，杂环会抑制光破碎途径。1a 与吡啶 (py) 形成正金属化复合物 [Ru 3 H(CO) 10 (C 5 H 4 N)] 2a。用锇可以分离出简单的取代产物[Os 3 (CO) 11 (py)]3b。用 2-甲基吡啶（mby）分别从 1a 和 1b 生成 [Ru 3 H(CO) 10 (2-MeC 5 H 3 N)] 5a 和 [Os 3 (CO) 11 (mpy)] 6b。在 2,6-二甲基吡啶中没有观察到净光反应。1a 和 1b 与 2,2′-联吡啶光解后生成 [M 3 (CO) 10 (bipy)]（M = Ru 7a 和 Os 7b）。通过单晶 X 射线衍射研究获得了 7b 的分子结构。1a 和 1b 与哒嗪（pydz）发生光解反应，生成取代产物 [M 3 (CO) 10 (pydz)]（M = Ru 8a 或 Os 8b）。
• Synthesis and structural characterization of the complexes [Os3(CO)10(CON3Ph)(NCMe)] and [Os3(CO)10(CON3Ph)(NC5H5)]
  作者：Kevin Burgess、Brian F. G. Johnson、Jack Lewis、Paul R. Raithby

  DOI：10.1039/dt9820002119

  日期：——

  The clusters [Os3(CO)11(NCMe)] and [Os3(CO)11(NC5H5)] have been treated with phenyl azide to give [Os3(CO)10(CON3Ph)(L)][L = NCMe (1) or NC5H5(2)], the structures of which in the solid state were established by X-ray crystallography. Complex (1) crystallises in space group P with a= 9.029(3), b= 12.720(5), c= 13.433(5)Å, α= 102.69(2), β= 102.52(2), γ= 104.75(2)°, and Z= 2. The structure was solved

  [Os 3（CO）11（NCMe）]和[Os 3（CO）11（NC 5 H 5）]簇已用叠氮化苯处理，得到[Os 3（CO）10（CON 3 Ph）（L ）] [L = NCMe（1）或NC 5 H 5（2）]，其固体结构通过X射线晶体学确定。配合物（1）在空间群P中结晶，其中a = 9.029（3），b = 12.720（5），c = 13.433（5）Å，α= 102.69（2），β= 102.52（2），γ= 104.75（ 2）°和Z＝ 2。通过直接方法和傅里叶差技术的组合来解决结构，并且对于3739个独特的衍射仪数据，通过块级联最小二乘法将其精炼为R＝ 0.057。配合物（2）在单斜空间群P 2 1 / n中结晶，其中a = 9.311（4），b = 16.707（11），c = 20.241（15）Å，β= 101.88（5）°，Z = 4 。使用与（1）相同的技术求解结构，并
• Synthesis of the carbido cluster [Os10(CO)24C]2? and the X-ray structure of [Os10(CO)24C][(Ph3P)2N]2
  作者：Peter F. Jackson、Brian F. G. Johnson、Jack Lewis、Mary McPartlin、William J. H. Nelson

  DOI：10.1039/c39800000224

  日期：——

  The carbido dianion [Os10(CO)24C]2– has been isolated from the pyrolysis of Os3(CO)11(py)(py = pyridine), and the pyrolysis of Os3(CO)12; an X-ray structural analysis of the [(Ph3P)2N]+ salt has shown a tetrahedral arrangement of ten metal atoms that is a fragment of a cubic close packed array.

  从Os 3（CO）11（py）（py =吡啶）的热解和Os 3（CO）12的热解中分离出碳二价阴离子[Os 10（CO）24 C] 2–。[[（Ph 3 P）2 N] +盐的X射线结构分析表明，十个金属原子的四面体排列是立方紧密堆积阵列的片段。
• Xue, Ming; Gao, Yi-Ci; Shen, Jian-Kun, Inorganica Chimica Acta, 1993, vol. 207, p. 207 - 212
  作者：Xue, Ming、Gao, Yi-Ci、Shen, Jian-Kun、Shi, Qi-Zhen、Basolo, Fred

  DOI：——

  日期：——
• Efficient microwave syntheses of the compounds Os3(CO)11L, L=NCMe, py, PPh3
  作者：Jade Y. Jung、Brittney S. Newton、Michelle L. Tonkin、Cynthia B. Powell、Gregory L. Powell

  DOI：10.1016/j.jorganchem.2009.06.041

  日期：2009.10

  The results of simple microwave-assisted ligand substitution reactions of Os-3(CO)(12) are reported. In a remarkably short period of time, the labile complex Os-3(CO)(11)(NCMe) is prepared in high yield without the need for a decarbonylation reagent such as trimethylamine oxide. Microwave irradiation of Os-3(CO)(12) in a relatively small amount of acetonitrile is shown to be a useful first step in two-step, one-pot syntheses of the cluster complexes Os-3(CO)(11)(py) and Os-3(CO)(11)(PPh3). (C) 2009 Elsevier B.V. All rights reserved.